Trisodium bis­{1-[iminio­(morpholino)meth­yl]guanidinium} bis­[hexa­hydrogen­hexa­molybdoaluminate(III)] chloride icosa­hydrate

نویسندگان

  • Feng Wang
  • Rui-Ge Cao
  • Yi-Bing Pan
  • Shu-Xia Liu
چکیده

In the title compound, Na(3)(C(6)H(15)N(5)O)(2)[Al(OH)(6)Mo(6)O(18)](2)Cl·20H(2)O, the [Al(OH)(6)Mo(6)O(18)](3-) polyoxo-anion has a B-type Anderson structure exhibiting approximate D(3d) symmetry. There are two types of sodium cations: the Na(+) cations of type I have a distorted octa-hedral coordination geometry formed by six O atoms and are statistically distributed over two positions with equal occupancies, while the coordination polyhedra of the two Na(+) cations of type II share one Cl anion located on an inversion center. The latter fragment, containing a Cl anion and two sodium cations, links two polyoxoanions into centrosymmetric blocks. The diprotonated 1-[imino-(morpholino)meth-yl]guanidinium cations and uncordinated water mol-ecules contribute to extensive N-H⋯O and O-H⋯O hydrogen bonding, resulting in the formation a three-dimensional supra-molecular structure.

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عنوان ژورنال:

دوره 64  شماره 

صفحات  -

تاریخ انتشار 2008